Undecacarbonyl-1κ3 C,2κ4 C,3κ4 C-[tris(2-chloroethyl) phosphite-1κP]-triangulo-triruthenium(0)
نویسندگان
چکیده
In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(12)Cl(3)O(3)P)(CO)(11)], one equatorial carbonyl ligand is substituted by a monodentate phosphite ligand, leaving one equatorial and two axial carbonyl ligands on one Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. In the crystal structure, the mol-ecules are linked into a one-dimensional column along [100] by inter-molecular C-H⋯O hydrogen bonds.
منابع مشابه
Undecacarbonyl-1κ3 C,2κ4 C,3κ4 C-(triethyl phosphite-1κP)-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(6)H(15)O(3)P)(CO)(11)], each Ru atom has distorted octa-hedral coord-ination geometry. The monodentate phosphine ligand is equatorially coordinated to one Ru atom, leaving one equatorial and two axial carbonyl substituents on the Ru atom. Each of the remaining two Ru atoms carries two equatorial and two axial carbonyl groups. In the crystal...
متن کاملUndecacarbonyl-1κ3 C,2κ4 C,3κ4 C-[tris(3-chlorophenyl)phosphine-1κP]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(18)H(12)Cl(3)P)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate phosphine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three benzene rings make dihedral angles of 87.83 (17),...
متن کاملUndecacarbonyl-1κ3 C,2κ4 C,3κ4 C-[tris(4-methylphenyl)arsine-1κAs]-triangulo-triruthenium(0)
In the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)As)(CO)(11)], one equatorial carbonyl group has been substituted by the monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on the Ru atom. The remaining two Ru atoms each carry two equatorial and two axial terminal carbonyl ligands. The three arsine-substituted phenyl rings make dihedral angles of ...
متن کاملUndecacarbonyl-1κ3 C,2κ4 C,3κ4 C-{tris[4-(methylsulfanyl)phenyl]arsine-1κAs}-triangulo-triruthenium(0)
The crystal structure of the title triangulo-triruthenium compound, [Ru(3)(C(21)H(21)AsS(3))(CO)(11)], confirms that during the synthesis one equatorial carbonyl ligand is substituted by a monodentate arsine ligand, leaving one equatorial and two axial carbonyl substituents on an Ru atom. The other two Ru atoms each carry two equatorial and two axial carbonyl ligands. The three arsine-substitut...
متن کاملDecacarbonyl-1κ3 C,2κ3 C,3κ4 C-bis[tris(3-chlorophenyl)phosphine]-1κP,2κP-triangulo-triruthenium(0) monohydrate
The asymmetric unit of the title triangulo-triruthenium compound, [Ru(3)(C(18)H(12)Cl(3)P)(2)(CO)(10)]·H(2)O, consists of one triangulo-triruthenium complex and one disordered water solvent molecule. Two of the 3-chloro-phenyl rings are disordered over two positions with refined site occupancies of 0.671 (3)/0.329 (3) and 0.628 (3)/0.372 (3). The water mol-ecule is disordered over two positions...
متن کامل